信息来源： 暂无 发布日期: 2016-09-08浏览次数:

姓名：陈利娟

职称：教授

导师情况：博士生导师

办公室：化学与分子科学学院429室

E-Mail：ljchen@henu.edu.cn

个人简介

陈利娟，中国科学院兰州化学物理研究所博士（2009）。教育部学位中心学位论文通讯评议专家，浙江、安徽等省自然科学基金通讯评议专家。

研究方向

主要从事多金属簇光电材料设计制备、性能及器件研究，在J. Mater. Chem. C、Nanoscale、Chem. Asian J.、Inorg. Chem.、Inorg. Chem. Front.、Cryst. Growth Des.、Dalton Trans.等国际知名期刊上发表学术论文80余篇。  

承担的主要项目

1. 氮杂环多羧酸参与构建的多钨氧酸盐过渡-稀土异金属簇聚物和框架材料的设计合成及其电化学生物传感性能研究(21871077)，国家自然科学基金面上项目，2019年1月至2022年12月，主持。

2. 含共轭电子有机功能配体调控的多核稀土离子嵌入的杂多钨氧簇材料的合成、结构、发光性能及发光机理研究(21671054)，国家自然科学基金面上项目，2017年1月至2020年12月，主持。

3. 以三价砷/锑/铋为杂原子多钨氧酸盐过渡-稀土异金属磁性材料的设计合成和性能研究(21301049)，国家自然科学基金，2014年1月至2016年12月，主持。

4. 杂多钼氧酸盐3d-4f异金属衍生材料的设计合成及其对偶氮类染料光降解性能研究(U1304208)，国家自然科学基金-河南人才培养联合基金，2014年1月至2016年12月，主持。

5. 有机无机复合钨氧簇基材料的设计及铁电磁性能研究(122300410106)，河南省科技厅自然科学基金，2012年1月至2014年12月，主持。

6. 含砷/锑多钨酸盐过渡-稀土异金属磁性材料的合成和性能(2014025)，河南省博士后一等资助，2015年4月至2017年6月，主持。

代表性成果

1. Jian-Cai Liu, Jie-Fei Wang, Qing Han, Ping Shangguan, Lu-Lu Liu, Li-Juan Chen, Jun-Wei Zhao,* Carsten Streb,* Yu-Fei Song,* Angew. Chem. Int. Ed. 2021, 61, 10.1002/ange.202017318.

2. Jian-Cai Liu, Qing Han, Li-Juan Chen, Jun-Wei Zhao,* Carsten Streb,* Yu-Fei Song*, Aggregation of Giant Cerium-Bismuth Tungstate Clusters into a 3D Porous Framework with High Proton Conductivity, Angew. Chem. Int. Ed. 2018, 57, 8416–8420.

3. Dan Wang, Lulu Liu, Jun Jiang, Lijuan Chen,* Junwei Zhao,* Polyoxometalate-based composite materials in electrochemistry: state-of-the-art progress and future outlook, Nanoscale, 2020, 12, 5705–5718.

4. Yan Zhang, Jun Jiang, Yifan Liu, Pan Li, Yong Liu, Lijuan Chen,* Junwei Zhao,* Multi-praseodymium-and-tungsten bridging octameric tellurotungstate and its 2D honeycomb composite film for detecting estrogen, Nanoscale, 2020, 12, 10842–10853.

5. Hailou Li, Chen Lian, Lijuan Chen,* Junwei Zhao,* Guo-Yu Yang,* Two unusual nanosized Nd³⁺-substituted selenotungstate aggregates simultaneously comprising lacunary Keggin and Dawson polyoxotungstate segments, Nanoscale, 2020, 12, 16091–16101.

6. Xin Xu, Xiaoyi Liu, Dan Wang, Xuejun Liu, Lijuan Chen,* Junwei Zhao*, {HPO₃} and {WO₄} Simultaneously Inducing Assembly of Tri-Ln(III)-Incorporated Antimonotungstates and Their Photoluminescence Behaviors, Inorg. Chem. 2021, 60, 1037−1044.

7. Baoxing Zeng, Yan Zhang, Yanhong Chen, Guoping Liu, Yanzhou Li,* Lijuan Chen,* Junwei Zhao*, 3-D Antimonotungstate Framework Based on 2,6-H₂pdca-connecting Iron-Cerium Heterometallic Krebs-type Polyoxotungstates for Detecting Small Biomolecules, Inorg. Chem. 2021, 60, 2663−2671.

8. Jinglin Liu, Dan Wang,* Xin Xu, Hailou Li, Junwei Zhao*, Lijuan Chen*, Multi-Nuclear Rare-Earth Implanted Tartaric Acid Functionalized Selenotungstates and Their Fluorescent and Magnetic Properties, Inorg. Chem. 2021, 60, 2533−2541.

9. Xin Xu, Hailou Li, Saisai Xie, Ling Mei, Ruru Meng, Lijuan Chen,* Junwei Zhao,* Double-oxalate−bridging tetralanthanide containing divacant Lindqvist isopolytungstates with energy transfer mechanism and luminous color adjustablility through Eu³⁺/Tb³⁺ cooping, Inorg. Chem. 2020, 59, 648-660.

10. Xin Xu, Ruru Meng, Changtong Lu, Ling Mei, Lijuan Chen,* Junwei Zhao,* Acetate-decorated tri-Ln(III)-containing antimonotungstates with a tetrahedral {WO₄} group as a structure-directing template and their luminescence properties, Inorg. Chem. 2020, 59, 3954−3963.

11. Dan Wang, Yamin Li, Yan Zhang, Xin Xu, Yong Liu, Lijuan Chen,* Junwei Zhao,* Construction of Ln³⁺-substituted arsenotungstates modified by 2,5-thiophenedicarboxylic acid and application in selective fluorescence detection of Ba²⁺ in aqueous solution, Inorg. Chem. 2020, 59, 6839-6848.

12. Huifen Hu, Jingjing Pang, Peijun Gong, Lijuan Chen,* Junwei Zhao,* Organic−inorganic 2-D hybrid networks constructed from pyridine-4-carboxylate-decorated organotin −lanthanide heterometallic antimotungstates, Inorg. Chem. 2020, 59, 11287-11297.

13. Jun Jiang, Lulu Liu, Guoping Liu, Dan Wang, Yan Zhang, Lijuan Chen,* Junwei Zhao,* An organic–inorganic hybrid cerium–encapsulated selenotungstate including three building blocks and its electrochemical detection to dopamine and paracetamol, Inorg. Chem. 2020, 59, 15355-15364.

14. Lulu Liu, Jun Jiang, Xiaoyi Liu, Guoping Liu, Dan Wang, Lijuan Chen,* Junwei Zhao,* First series of mixed (P^III, Se^IV)-heteroatoms oriented rare-earth embedded polyoxotungstates containing distinct building blocks, Inorg. Chem. Front. 2020, 7, 4640-4651.

15. Yamin Li, Hailou Li, Jun Jiang, Lijuan Chen,* Junwei Zhao,* Three types of distinguishing L-alanine-decorated and rare-earth-incorporated arsenotungstate hybrids prepared in a facile one-step assembly strategy, Inorg. Chem. 2019, 58, 3479–3491.

16. Yan Zhang, Yamin Li, Jingjing Pang, Yifan Liu, Pan Li, Lijuan Chen,* Junwei Zhao,* Two penta-RE^III encapsulated tetravacant Dawson selenotungstates and nanoscale derivatives and their luminescence properties, Inorg. Chem. 2019, 58, 7078−7090.

17. Hai-Lou Li, Chen Lian, Li-Juan Chen,* Jun-Wei Zhao,* Guo-Yu Yang,* Two Ce³⁺-substituted selenotungstates regulated by N,N-dimethylethanolamine and dimethylamine hydrochloride, Inorg. Chem. 2019, 58, 8442−8450.

18. Xin Xu, Yanhong Chen, Yan Zhang, Yifan Liu, Lijuan Chen,* Junwei Zhao*, Rare-earth and antimony-oxo clusters simultaneously connecting antimonotungstates comprising divacant and tetravacant Keggin fragments, Inorg. Chem. 2019, 58, 11636−11648.

19. Jing-Lin Liu, Meng-Tian Jin, Li-Juan Chen,* Junwei Zhao*, First dimethyltin- functionalized rare-earth incorporated tellurotungstates consisting of {B-α-TeW₇O₂₈} and {W₅O₁₈} mixed building units, Inorg. Chem. 2018, 57, 12509–12520.

20. Yanhong Chen, Longhui Sun, Shenzhen Chang, Lijuan Chen,* Junwei Zhao*, Lanthanide nature and various coordination mode of 2-picolinic acid ligand tuning three types of rare 3d−4f heterometallic tungstoantimonates, Inorg. Chem. 2018, 57, 15079−15092.

21. Qing Han, Jian-Cai Liu, Yue Wen, Li-Juan Chen,* Jun-Wei Zhao,* Guo-Yu Yang*, Tellurotungstate-based organotin−rare-earth heterometallic hybrids with four organic components, Inorg. Chem. 2017, 56, 7257–7269.

22. Qing Han, Yue Wen, Jian-Cai Liu, Wu Zhang, Li-Juan Chen,* Jun-Wei Zhao,* Rare-Earth-Incorporated Tellurotungstate Hybrids Functionalized by 2-Picolinic Acid Ligands: Syntheses, Structures, and Properties, Inorg. Chem. 2017, 56, 13228−13240.

23. Hailou Li, Yajie Liu, Rui Zheng, Lijuan Chen,* Jun-Wei Zhao,* Guo-Yu Yang*, Trigonal pyramidal {AsO₂(OH)} bridging tetra-nuclear rare-earth encapsulated polyoxotungstate aggregates, Inorg. Chem. 2016, 55, 3881−3893.

24. Jiancai Liu, Jie Luo, Qing Han, Jing Cao, Lijuan Chen,* You Song,* Junwei Zhao,* Coexistence of long-range ferromagnetic ordering and spin-glass behavior observed in the first inorganic–organic hybrid 1-D oxalate-bridging nona-Mn^II sandwiched tungstoantimonate chain, J. Mater. Chem. C, 2017, 5, 2043–2055.

25. Yan Zhang, Yi-Fan Liu, Xin Xu, Li-Juan Chen*, Jun-Wei Zhao,* Preparations, structures and luminescence properties of penta-rare-earth incorporated tetra-vacant Dawson selenotungstates and their Ho³⁺/Tm³⁺ co-doped derivatives, Chem. Asian J. 2020. 15, 1156-1166.

26. Hai-Lou Li, Ya-Jie Liu, Ya-Min Li, Li-Juan Chen,* Jun-Wei Zhao,* Guo-Yu Yang*, Unprecedented Selenium and Lanthanide Simultaneously Bridging Selenotungstate Aggregates Stabilized by Four Tetra-vacant Dawson-like {Se₂W₁₄} Units, Chem. Asian J. 2018, 13, 2897–2907.

27. Pei-Jun Gong, Jing-Jing Pang, Hui-Fen Hu, Hui-Jie Li, Li-Juan Chen,* Jun-Wei Zhao*, Ligand-Controlled Assembly of Heteropolyoxomolybdates Constructed from Plenary Keggin Germanomolybdates and Cu-Ln Heterometallic Units, Chem. Asian J. 2018, DOI: 10.1002/asia.201801255.

28. Ya-Jie Liu, Meng-Tian Jin, Li-Juan Chen*, Jun-Wei Zhao*, Recent advances in isopolyoxotungstates and their derivatives, Acta Cryst. 2018, C74, 1202–1221.

29. Yan Zhang, Dan Wang, Baoxing Zeng, Lijuan Chen,* Junwei Zhao,* Guo-Yu Yang*, An unprecedented polyhydroxycarboxylic acid ligand bridging multi-Eu^III incorporated tellurotungstate and its luminescence properties, Dalton Trans. 2020, 49, 8933–8948.

30. Xin Xu, Changtong Lu, Saisai Xie, Lijuan Chen,* Junwei Zhao,* A trimeric tri-Tb³⁺-including antimonotungstate and its Eu³⁺/Tb³⁺/Dy³⁺/Gd³⁺ codoped species with luminescence properties, Dalton Trans. 2020, 49, 12401–12410.

31. Huijie Li, Peijun Gong, Jun Jiang, Yamin Li, Jingjing Pang, Lijuan Chen,* Junwei Zhao,* Organic–inorganic hybrids assembled from plenary Keggin-type germanotungstate units and 3d–4f heterometal clusters, Dalton Trans. 2019, 48, 3730–3742.

32. Xing Ma, Hailou Li, Lijuan Chen*, Junwei Zhao*, The main progress over the past decade and future outlook on high-nuclear transition-metal substituted polyoxotungstates: from synthetic strategies, structural features to functional properties, Dalton Trans. 2016, 45, 4935–4960.

33. Jiancai Liu, Jing Yu, Qing Han, Yue Wen, Lijuan Chen,* Junwei Zhao,* First quadruple-glycine bridging mono-lanthanide-substituted borotungstate hybrids, Dalton Trans. 2016, 45, 16471–16484.

34. Lijuan Chen, Fang Zhang, Xing Ma, Jie Luo, Junwei Zhao*, Two types of novel tetra-iron substituted sandwich-type arsenotungastates with supporting lanthanide pendants, Dalton Trans. 2015, 44, 12598–12612.

35. Jun Jiang, Jiaru Duan, Jiancai Liu, Lijuan Chen,* Junwei Zhao,* Lanthanide-incorporated borotungstates including Keggin-type [BW₁₁O₃₉]^9– fragments and their luminescence properties, Cryst. Growth Des. 2020, 20, 362−369.

36. Yajie Liu, Hailou Li, Changtong Lu, Peijun Gong, Xiaoyun Ma, Lijuan Chen,* Junwei Zhao*, Organocounterions-assisted and pH-controlled self-assembly of five nanoscale high-nuclear lanthanide substituted heteropolytungstates, Cryst. Growth Des. 2017, 17, 3917−3928.

37. Xiuhua Wang, Yajie Liu, Mengtian Jin, Yuxing Wu, Lijuan Chen,* Jun-Wei Zhao*, Two families of rare-earth-substituted Dawson-type monomeric and dimeric phosphotungstates functionalized by carboxylic ligands, Cryst. Growth Des. 2017, 17, 5295–5308.

38. Hailou Li, Wen Yang, Xiuhua Wang, Jianru Ma, Lijuan Chen,* Junwei Zhao*, Self-assembly of a family of isopolytungstates induced by the synergistic action of lanthanoids and pH variation in the process of reaction: syntheses, structures and properties, Cryst. Growth Des. 2016, 16, 108–120.

39. Jun-Wei Zhao,* Jing-Li Zhang, Yan-Zhou Li, Jing Cao, Li-Juan Chen*, Novel one-dimensional organic−inorganic polyoxometalate hybrids constructed from heteropolymolybdate units and copper−aminoacid complexes, Cryst. Growth Des. 2014, 14, 1467−1475.

40. Jun-Wei Zhao,* Jing Cao, Yan-Zhou Li, Jing Zhang, Li-Juan Chen,* First tungstoantimonate-based transition-metal–lanthanide heterometallic hybrids functionalized by aminoacid ligands, Cryst. Growth Des. 2014, 14, 6217-6229.

41. Junwei Zhao,* Hailou Li, Yanzhou Li, Chunyang Li, Zhenling Wang, Lijuan Chen,* Rectangle versus square oxalate-connective tetra-lanthanide cluster anchored in lacunary Lindqvist isopolytungstates: syntheses, structures and properties, Cryst. Growth Des. 2014, 14, 5495−5505.

42. Junwei Zhao,* Dongying Shi, Lijuan Chen,* Pengtao Ma, Jingping Wang, Jian Zhang,* Jingyang Niu,* Tetrahedral polyoxometalate nanoclusters with tetrameric rare-earth cores and germanotungstate vertexes, Cryst. Growth Des. 2013, 13, 4368−4377.

43. Peijun Gong, Yanyan Li, Cuiping Zhai, Jie Luo, Xuemeng Tian, Lijuan Chen*, Junwei Zhao,* Syntheses, structural characterization and photophysical properties of two series of rare-earth-isonicotinic-acid containing Waugh-type manganomolybdates, CrystEngComm, 2017, 19, 834–852.

44. Jiancai Liu, Qing Han, Lijuan Chen,* Junwei Zhao,* A brief review of the crucial progress on heterometallic polyoxotungstates in the past decade, CrystEngComm, 2016, 18, 842–862.

45. Lijuan Chen, Jing Cao, Xinghua Li, Xing Ma, Jie Luo, Junwei Zhao*, The First purely inorganic polyoxotungstates constructed from dimeric tungstoantimonate-based iron–rare-earth heterometallic fragments, CrystEngComm, 2015, 17, 5002–5013.

46.Xing Ma, Wen Yang, Lijuan Chen*, Junwei Zhao*, Significant developments on rare-earth-containing polyoxometalate chemistry: synthetic strategies, structural diversities and correlative properties, CrystEngComm, 2015, 17, 8175-8197.

授权专利

1. 陈利娟，赵俊伟，刘雅洁，陈艳红，二元有机羧酸参与的铁-镝异金属锑钨酸盐框架材料及其制备方法与应用，中国发明专利, 专利号：ZL 2018 1 0082337.X，专利申请日，2018年1月29日，授权公告日，2020年12月25日，证书号：4170715。

2. 陈利娟，罗婕，马鹏涛，赵俊伟，谢志刚，马杏，李海楼，一种十核铽取代砷钨氧酸盐纳米簇合物及其制备方法和应用，中国发明专利, 专利号，ZL 2015 1 0787718. 4，专利申请日：2015年11月17日，授权公告日：2017年12月1日， 证书号：2723239。

3．赵俊伟，陈利娟，陈艳红，孙龙辉，具有能量转移的芳香羧酸修饰的过渡稀土异金属嵌入的锑钨氧酸盐材料、制备方法及应用，中国发明专利, 专利号：ZL 2018 1 0932965.2，专利申请日，2018年8月16日，授权公告日，2020年9月1日，证书号：3964442。

4. 赵俊伟，陈利娟，刘敬琳，金梦添，一种二甲基锡功能化且包含多酸混合构筑块铒嵌入碲钨酸盐材料基其制备方法与应用，中国发明专利, 专利号：ZL 2018 1 0686236.3，专利申请日，2018年6月28日，授权公告日，2020年10月2日，证书号：4015576。

5. 李明雪，陈利娟，罗婕，赵俊伟，刘建彩，张芳，铜-铕异金属取代砷酸盐及其制备方法和应用，专利申请日：2015年1月23日，专利授权日：2016年4月27日，专利号，ZL 2015 1 0035099. 3. 证书号：2047539。

6. 赵俊伟，刘勇，陈利娟，罗婕，史岽瑛，牛景杨，王敬平，有机-无机杂化过渡-稀土异金属取代锗钨酸盐晶态储氢材料及其制备方法，中国发明专利, 专利号：ZL 2012 1 0423422.0, 专利申请日，2012年10月30日，授权公告日，2014年4月16日，证书号：1388525。

7. 赵俊伟，罗婕，陈利娟，刘建彩，曹静，刘雅洁，具有自旋玻璃行为的铁磁性有机-无机杂化九核锰取代的夹心型锑钨氧酸盐、制备及应用，中国发明专利, 专利号：ZL 2016 1 0691831.7，专利申请日，2016年8月19日，授权公告日，2019年1月4日，证书号：3204699。