信息来源： 发布日期: 2018-06-08浏览次数:

题 目: A high-nuclearity isopolyoxotungstate based manganese cluster: one-pot synthesis and step-by-step assembly

作 者: Chao Zhang, Mengrui Zhang, Hongyu Shi, Qingdao Zeng, Dongdi Zhang, Yaqing Zhao, Yuan Wang, Pengtao Ma, Jingping Wang *and Jingyang Niu *

刊 名:Chemical Communications

年卷页: 2018, 54, 5458--5461

影响因子：6.319

摘 要：A manganese(III,IV)–tungsten(VI) supercluster based on 72 manganese ions (48 Mn^IV and 24 Mn^III) and 48 tungsten(VI) centers [{Mn^IV₂₄Mn^III₁₂O₂₈(H₂O)₂₃}₂(W₂₄O₁₂₀)₂]⁴⁰⁻ has been prepared from the carboxylic Mn₁₂ cluster. Its structure comprises two unprecedented cage-like Mn₃₆W₂₄ cores linked via two Mn–O–W bonds, leading to a Mn₇₂W₄₈ assembly. The inorganic synthetic mechanism was investigated through different synthesis methods and comprehensive ESI-MS tests.

 文章链接：http://pubs.rsc.org/en/Content/ArticleLanding/2018/CC/C8CC01622D#!divAbstract.