题 目: Two novel telluroniobates with efficient catalytic activity for the imidation/amidation reaction
作 者: Mengyuan Cheng, Yufeng Liu, Nan Li, Jingwen Shi, Weixin Du, Dongdi Zhang,* Guoping Yang,* Guan Wang and Jingyang Niu*
刊 名: Chem. Commun.
年卷页:2022, 58, 1167−1170
影响因子：6.222
摘 要：We present the synthesis and catalytic properties of two novel telluroniobates {Te15Nb21} and {Te10Nb14}. {Te15Nb21} is the first trimeric telluroniobate with the largest number of tellurium atoms in the Te–Nb system. Besides, both clusters exhibit excellent catalytic activity in the amidation reactions of anhydrides and amines, and cyclic imides and bi-amides can be controllably synthesized, which represents a breakthrough in the catalysis of polyoxoniobates.
