题 目:A Rh-substituted polyoxometalate with an acetate modified building block {As2W22O76(CH3COO)2}
作 者:Zhen Liu, Xue Zhang, Rong Wan, Huafeng Li, Yumei Hong, Pengtao Ma, Jingyang Niu * and Jingping Wang *
刊 名:Chem. Commun.
年卷页:2021,57,10250-10253.
影响因子：5.996
摘 要：The first example of Rh-substituted organic–inorganic hybrid arsenotungstate [H2N(CH3)2]8{[Na(H2O)4]NaAs2W22(CH3COO)2O76Rh2(N(CH3)2)2}·H2O (1) synthesised in an aqueous solution by the conventional method is reported. Two [Rh(N(CH3)2)]3+ fragments are imbedded into the vacancy of the [NaAs2W22(CH3COO)2O76]15- unit by Rh–As bonds [2.439(1) Å], which are observed in POM chemistry for the first time.
文章链接：https://pubs.rsc.org/en/results/journals?Category=journal&AllText=10.1039%2F%20d1cc03646g&IncludeReference=false&SelectJournal=True&ArtRefJournalName=Chemical%20Communications%3B&DateRange=false&SelectDate=false&PriceCode=False&OpenAccess=false&JournalName=Chemical%20Communications
