题 目:Discovery of two Na+-centered Silverton-type polyoxometalates {NaM12O42} (M = Mo, W)
作 者:Rong Wan, Zhen Liu, Xinyi Ma, Huafeng Li, Pengtao Ma, Chao Zhang, Jingyang Niu * and Jingping Wang *
刊 名:Chem. Commun.
年卷页:2021,57,2172-2175.
影响因子：5.996
摘 要：Two new members of highly charged Silverton archetype [NaM12O42]11- were demonstrated in the 3D POM-based frameworks Na3[NaM12O42(Ru(DMSO)3)4] ·13H2O (M = Mo (1), W (2)), where the unusual icosahedron coordination of a Na+ ion incubated as a heteroatom is reported for the first time in topical POMs. Furthermore, 23Na NMR was applied to certify the interpretation of X-ray diffraction data concerning Na localization. Additionally, the porous nature of the frameworks 1 and 2 has also been investigated.
文章链接：https://pubs.rsc.org/en/results/journals?Category=journal&AllText=10.1039%2Fd0cc07590f&IncludeReference=false&SelectJournal=True&ArtRefJournalName=Chemical%20Communications%3B&DateRange=false&SelectDate=false&PriceCode=False&OpenAccess=false&JournalName=Chemical%20Communications
