题 目: A Large Molecular Cluster with High Proton Release Capacity
作 者: Dongdi Zhang, Hui Li, Chen Li, Zehao Wang, Tao Li, Nan Li, Mengyuan Cheng, Jingping Wang, Jingyang Niu, * and Tianbo Liu *
刊 名: Chem. Commun.
影响因子：5.996
年卷页: 2020,56,12849-12852.
摘 要：We present a single molecular polyoxometalate cluster (K41[(P2W12Nb6O62)6{Mn3(OH)3(H2O)6}4{Mn3Na(H2O)16}]·26H2O) with controllable releasing large amounts of protons (~40 permolecule) in its aqueous solution upon addition of a base. The deprotonation/protonation process is reversible with the clusters remaining intact. This molecule can also absorb up to 11 protons per cluster when acid HCl was added into its original aqueous solution. To best of our knowledge, such large proton absorption/release capacity along with excellent stability is unprecedented.
文章链接：https://pubs.rsc.org/en/content/articlelanding/2020/cc/d0cc04763e#!divAbstract
