信息来源： 暂无 发布日期: 2016-07-22浏览次数:

姓名：韩秋霞                

职称：教授                

导师情况：硕士/博士生导师                

办公室：化学与分子科学学院118室                

E-Mail：hdhqx@henu.edu.cn                

个人简介                

   韩秋霞，河南沈丘县人，教授，博士生导师。河南省优秀青年基金获得者、河南省教育厅学术技术带头人、开封市科技创新人才、开封市科技创新团队带头人。           

研究方向                

多酸基功能配合物；多酸催化。           

承担的主要项目(近五年)                

1. 河南省2022年度第二批省级科技研发计划联合基金重点项目，225200810027，手性有机膦基介孔晶态材料的精准构建及不对称合成芴类轴手性核心骨架中的应用，2023.10−2026.10，75万，在研。

2.国家自然科学基金青年项目，21601048，多酸基手性功能材料的制备及不对称串联催化烯烃制备环状碳酸酯的研究，2017.01-2019.12，25万元，完成。

3. 国家自然科学基金-河南人才培养联合基金，U1304201，基于多金属氧酸盐的手性金属有机框架在不对称催化缺电子烯烃环氧化中的应用，2014.01-2016.12，30万元，结项。

4. 河南省优秀青年科学基金，手性光催化剂的合成及光氧化还原催化醛酮的不对称α-烷基化研究，2020.10-2023.09，202300410043，25万，在研。

5. 河南省高等学校重点科研项目，20zx006，新型多功能手性催化剂的合成及在不对称光催化高效合成重要化学品中的应用，30万，2020.01-2021.12，在研。           

代表性成果                

代表性论文（按时间倒序）：

1.Ting Zhang, Jiachen Jiao, Kaixin Guo, Lei Zhang, Chuanbao Zhang, Qiuxia Han,* Photocatalytic Oxidative Coupling of Terminal Alkynes with p-Benzoquinone to Diaryl Ketones by the Cu(I)-PS-POM Assembling System through Synergistic Effect, J Catal. 2024, 429, 115287. (SCI 一区)

2. Chen Si, Xueling Liu, Junjie Xu, Jiangbo Xu, Pengtao Ma, Qiuxia Han,* Designing a Binuclear Copper Center-Incorporated Photocatalyst to Simulate Enzyme Catalysis in Aerobic Hydroxylation of Phenylboronic Acids, Inorg. Chem. Front., 2023, 10, 6936. (SCI 一区)

3. Jiachen Jiao, Ting Zhang, Jiangbo Xu, Kaixin Guo, Jie Li and Qiuxia Han* , Hydroxyl Radical-dominated Selective Oxidation of Ethylbenzene over a Photoactive Polyoxometalate-based Metal-organic Framework, Chem. Commun., 2023, 59, 3114-3117.(SCI 二区, NI)

4. Xiaomei Yan, Jiangbo Xu, Ting Zhang, Chen Si, Jiachen Jiao, Jie Li, Qiuxia Han,*Designing polyoxometalate-based metal-organic framework for oxidation of styrene and cycloaddition of CO2 with epoxides, Chinese Chem. Lett., 2023, 34, 107851. (SCI 一区)

5. Chen Si, Xueling Liu, Ting Zhang, Jiangbo Xu, Jie Li, Jiya Fu,* Qiuxia Han^* Constructing a Photocatalyst for Selective Oxidation of Benzyl Alcohol to Benzaldehyde by Photo-Fenton-like Catalysis, Inorg.Chem., 2023, 62, 4210-4219. (SCI 二区, NI/top)

6. Jiachen Jiao, Hui Sun, Chen Si, Jiangbo Xu, Ting Zhang, Qiuxia Han,* Photocatalytic Multielectron Reduction of Nitroarenes to Anilines by Utilizing Electron-storable Polyoxometalate-based Metal-organic Framework, ACS Appl. Mater. Interfaces, 2022, 14, 16386-16393.(SCI 二区, top)

7. Chen Si, Fan Liu, Xiaomei Yan, Jiangbo Xu, Guiqin Niu, Qiuxia Han,* Designing Polyoxometalate-incorporated Metal-organic Frame-work for Reduction of Nitroarenes to Anilines by Sequential Proton-Coupled Electron Transfers, Inorg. Chem., 2022, 61, 5335-5342.

8. Jiachen Jiao, Xiaomei Yan, Songzhu Xing, Ting Zhang, and Qiuxia Han,* Design of a Polyoxometalate-Based Metal-Organic Framework for Photocatalytic C(sp3 )−H Oxidation of Toluene, Inorg. Chem., 2022, 61, 2421-2427.(SCI 二区, NI/top)

9. Xiaomei Yan, Zhuolin Shi, Jiachen Jiao, Chen Si, Qiuxia Han*, An Isopolymolybdate-Incorporated Metal-Organic Framework with Sulfite Oxidase-Mimicking Activity for Photocatalytic Oxidation of Sulfides Utilizing In Situ-Generated Singlet Oxygen, Inorg. Chem., 2021, 60, 16810-16816. (SCI 二区, NI/top)

10. Chen Si, Pengtao Ma,* Qiuxia Han,* Jiachen Jiao, Wei Du, Jingpin Wu, Mingxue Li, and Jingyang Niu*. A Polyoxometalate-based Inorganic Porous Material with both Proton and Electron Conductivity by Light Actuation: Photocatalysis for Baeyer−Villiger Oxidation and Cr(VI) Reduction. Inorg. Chem., 2021, 60, 682-691. (SCI 二区, NI/top)

11. Jie Li, Jiachen Jiao, Jiangnan Chang, Mingxue Li,* and Qiuxia Han,* Visible-Light-Driven C−N Bond Formation by a Hexanickel Cluster Substituted Polyoxometalate-Ba sed Photocatalyst, Inorg. Chem., 2021, 60, 10022-10029. (SCI 二区, NI/top)

12. Jiachen He, Jie Li, Qiuxia Han,* Chen Si, Guiqin Niu, Mingxue Li, Jingping Wang, Jingyang Niu, Photoactive Metal-Organic Framework for the Reduction of Aryl Halides by the Synergistic Effect of Consecutive Photo-Induced Electron-Transfer and Hydrogen-Atom Transfer Processes, ACS Appl. Mater. Interfaces, 2020, 12, 2199-2206.(SCI 一区top)

13. Jie Li, Jiachen He, Chen Si, Mingxue Li,* Qiuxia Han,* Ziliang Wang, Junwei Zhao，Special-Selective C–H Oxidation of Toluene To Benzaldehyde by a Hybrid Polyoxometalate Photocatalyst Including a Rare [P₆W₄₈Fe₆O₁₈₀]^30– Anion, J Catal., 2020, 392, 244-253. (SCI 一区)

14. Jiachen He,^† Qiuxia Han,*^,† Jie Li, Zhuolin Shi, Xiaoyun Shi, Jingyang Niu,* Ternary Supramolecular System for Photocatalytic Oxidation with Air by Consecutive Photo-induced Electron Transfer Processes, J. Catal., 2019, 376, 161-167.  (SCI 一区)

15.Zhuolin Shi, Jiachen Jiao, Qiuxia Han,* Yang Xiao, Laikuan Huang, Mingxue Li. Synthesis Cu(I)–CN-based MOF with in-situ generated cyanogroup by cleavage of acetonitrile: Highly efficient for catalytic cyclization of propargylic alcohols with CO2. Mol. Catal., 2020, 496, 111190. (SCI 二区, NI/top)

16. Qiuxia Han, Bo Qi, Weimin Ren, Cheng He, Jingyang Niu, Chunying Duan.* Polyoxometalate-Based Homochiral Metal-Organic Frameworks for Tandem Asymmetric Transformation of Cyclic Carbonates from Olefins. Nat. Commun., 2015, 6, 10007. (SCI一区)

17. Qiuxia Han, Cheng He, Min Zhao, Bo Qi, Jingyang Niu, Chunying Duan.* Engineering Chiral Polyoxometalate Hybrid Metal-organic Frameworks for Asymmetric Dihydroxylation of Olefins. J. Am. Chem. Soc., 2013, 135, 10186-10189. (SCI 一区)

授权专利                

1. 一类缺位型多酸基金属有机框架分子材料及其在光催化选择性还原硝基苯的应用，中国，发明专利，专利号：ZL 2022 1 0009328.4 授权日期：2023.03.24。

2. 一种手性多酸基金属有机框架材料及其制备方法和应用，中国，发明专利，专利号：ZL 2019 1 0209209.1, 授权日期：2021.10.12。

3. 一类富电子体系的金属有机框架分子材料及其在光催化还原重金属离子中的应用，中国，发明专利，专利号：ZL 2019 1 1324193.5，授权日期：2021.06.29。

4. 基于Zn取代Keggin型杂多钨酸盐的有机-无机复合物、合成方法及应用，中国，发明专利，专利号：ZL 2019 1 0496900.2，授权日期：2021.04.23。

5. 一种亲水性无机多孔材料、制备方法及其在选择性催化醛或酮与羟胺反应方面的应用，中国，发明专利，专利号：ZL 2017 1 0352407.4，授权日期：2019.07.05。